Nope, it doesn't work that way. On the ported vacuum, the second the throttle comes off idle, the vacuum canister pulls in full vacuum. It's not a variable-rate thing--like I said, it's an on/off switch. Connecting the spark vacuum to the wrong port absolutely, positively cannot cause the problems he's having. If you don't believe me, get two vacuum gauges and connect one to full manifold vacuum, and tee the other in with your ported spark to the distributor. The second you move the accelerator pedal, no matter under what load you put it the two gauges will have identical readings. The only difference between the two sources is that the ported spark opening is above the throttle plates, and the full manifold vacuum is below them. Once the throttle plate is opened even the slightest bit, the vacuum is equalized above and below the throttle plates and they will read the same on a gauge.
The only thing you'll get with the vacuum advance hooked to the wrong port is an erratic idle. I added a ported vacuum to the lean-burn ThermoQuad that was on my Charger prior to the Six Pack, and the only gain was a consistent idle (that's why I did it).
Knowing it did this prior to the swap is helpful--I had not mentioned the timing-chain thing because I thought it ran fine previously. 68R/T has a good point there; a timing-set swap is probably in order. Use only a double-row roller set; done flat-rate style it's a sub-2-hour-job. You don't even have to remove the alternator on a big-block... just remove the adjustment bracket and swing it out of the way.
Though I still think it's an intake leak, I'd probably replace the timing set. With the right incentive, I've done both (on my 440) in less than two hours. Come to think of it, I also swapped the cam when I did that. The B/RB Chrysler has got to be the all-time easiest engine to service.